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Created June 17, 2015
Last modified February 16, 2016
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Description

Circuit to determine the voltage drop in solution and the voltage drop at the electrochemical interface. Current is controlled by the voltage V2 and R7. The time-dependent output show that the measured voltage across the whole cell is in two parts, one (R1+R3)*I dropping rapidly and the other (R2//C2) decaying more slowly. In addition, simulating the frequency response shows that the same information can be obtaining with a sin wave source. R1 is the resistance of the wire and electrical contact in the working electrode, a carbon fiber. R2//C2 is the interface, R3//C3 is the bulk solution and C1//R4 is the reference electrode. No potentiostat here.


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